Toxicologia Ambiental e Analítica

Survey of Glyphosate Residues in Honey, Corn and Soy Products

Abstract

Fernando Rubio, Emily Guo and Lisa kamp

Samples of honey (sixty nine), pancake and corn syrup (twenty six), soy sauce (twenty eight), soy milk (eleven), and tofu (twenty) purchased in the Philadelphia, US metropolitan area were analyzed for glyphosate residue using ELISA. The limit of quantification (LOQ) and range of the method were determined for honey, pancake syrup, and corn syrup to be 15 to 800 ppb; soy sauce, soy milk, and tofu 75 to 4,000 ppb. Glyphosate residues above the limit of quantification were not found in pancake and corn syrup, soy milk, and tofu. Of the sixty-nine honey samples analyzed, forty-one samples, or fifty-nine percent (59%), had glyphosate concentrations above the method LOQ (15 ppb), with a concentration range between 17 and 163 ppb and a mean of 64 ppb. Eleven of the tested honey samples were organic; five of the organic honey samples, or forty-five percent (45%), contained glyphosate concentrations above the method LOQ, with a range of 26 to 93 ppb and a mean of 50 ppb. Of the fifty-eight non-organic honey samples, thirty-six samples, or sixty-two percent (62%), contained glyphosate concentrations above the method LOQ, with a range of 17 to 163 ppb and a mean of 66 ppb. In addition to comparison of production method (organic vs. conventional), the honey results were evaluated according to pollen source and by country of origin, grouped by GMO usage (prohibited, limited, or permitted). Glyphosate concentrations above the method LOQ (75 ppb) were also found in ten of the twenty-eight soy sauce samples evaluated (36%), with a concentration range between 88 and 564 ppb and a mean of 242 ppb; all organic soy sauce samples tested were below the method LOQ.